In this dissertation, the stable radical cation salts ofphenothiazine and 10 - alkylphenothiazine alky=〓(〓 hexachloroantimonate,perchlorate and iodide were prepared by one- electron oxidationwith 2,2,6,6-tetramethyl - 4 -acetyloxypiperidine oxoammoniumhexachloroantimonate, perchloric acid/hydrogen peroxide andmolecular iodine respectively, and they were characteried by UV -Vis spectroscopy and ESR spectroscopy.

本文的主要內(nèi)容有：吩噻嗪和10-烴基吩噻嗪分別被碘人人操人人爱人人草、高氯酸／過氧化氫91av在线观看91，2欧洲熟女另类，2日本人成精品视频在线，6，6-四甲基-4-乙酰氧基哌啶氧銨六氯銻酸鹽氧化為相應(yīng)的正離子自由基碘鹽亚洲网中文字幕、高氯酸鹽、六氯銻酸鹽，并用UV-Vis光譜和ESR波譜進(jìn)行了鑒定和研究在线鲁一鲁。

The effects of above-mentionedconditions on alkylene reaction are studied to obtain the optimum reactive conditionsby orthogonal experiments having seven factors and three levels. GCLE is chosen as material to prepare 7-phenyl acetamideyl vinyl cephalkyl acidp-methoxy benyl eatsr in the experiment. The process is as follow: GCLE reacts withiodide in solvent, and produce 3-iodid, then reacts with PPh_3 to produce Witting agent,and reacts with HCHO to produce 7-phenyl acetamideyl vinyl cephalkyl acid p-methoxy benyl eatsr in alkaline conditions.

試驗(yàn)選用GCLE作為原料制備7-苯乙酰氨基-3-乙烯基頭孢烷酸對(duì)甲氧芐酯，反應(yīng)過程如下：GCLE與碘化物9999在线、PPh3在溶劑中反應(yīng)生成3位膦鹽黄色在线视频网站国产，在堿性條件下生成Wittig試劑再與HCHO反應(yīng)生成7-苯乙酰氨基-3-乙烯基頭孢烷酸對(duì)甲氧芐酯。

A selective and mild PS-DIB/ionic-liquid immobilized 2, 2, 6, 6-tetramethyl-piperidin-4-ol-N-oxyl catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via the iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TeMPO catalyst, 4-(2, 2, 6, 6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from TeMPO and 1, 4-dibromobutane.

將聚苯乙烯樹脂先碘化再乙跖访阑粕悠礎一级黄色视频；拦患痘善频昧素?fù)載型二乙酰氧碘苯作為氧化劑。2丝袜美腿视频无码二区30p， 2欧美轮奸网， 6， 6-四甲基－N-氧自由基哌啶醇與118禁无码黄片， 4-二溴丁烷反應(yīng)生成4-溴丁氧基－2毛片A级片黄片， 2， 6my国产精品免费， 6-四甲基－哌啶－1-氧化物欧美操逼打开直接看的黄片，再與N-甲基咪唑發(fā)生季銨化反應(yīng)，生成的溴化季銨鹽與四氟硼酸鈉進(jìn)行離子交換制得氟硼酸型2国语对白肏屄视频， 2在线看免费A√片， 6， 6-四甲基－N-氧自由基哌啶負(fù)載離子液體国产.com。

A selective and mild PS-DIB/ionic-liquid immobilized TEMPO catalytic oxidation procedure of alcohols to the corresponding aldehydes and ketones in ionic liquid BF4 at room temperature was developed. The oxidant PS-DIB was prepared via Iodation and acetylation of polystyrene resin. For the preparation of the ionic-liquid immobilized TEMPO catalyst, 4-(2,2,6,6-Tetramethyl-1-oxyl-4-piperidoxyl)butyl bromide was first synthesized from 2,2,6,6-tetramethyl-piperidin-4-ol-N-oxyl and 1,4-dibromobutane.

將聚苯乙烯樹脂先碘化再乙跞顺墒悠得夥咽悠翟谙吖劭床シ牛基化，制得了負(fù)載型二乙酰氧碘苯(diacetoxyiodo polystyrenese哟哟在线观看，PS-DIB)作為氧化劑男人直接插女人下面黄视频在线播放。2，2日韩精品影视系列在线播放，6国产一级AV网站在线，6-四甲基-N-氧自由基哌啶醇(2，2日本免費黃色網站com，6www4438，6-tetramethyl-piperidin-4-ol-N-oxyl，TEMPO)與1黄色视频在线播放特级a级，4-二溴丁烷反應(yīng)生成4-溴丁氧基-2女人被草视频，2国际a极性爱片，6，6-四甲基-哌啶-1-氧化物被操高潮了视频，再與N-甲基咪唑發(fā)生季銨化反應(yīng)全网高清国产AV网站，生成的溴化季銨鹽與四氟硼酸鈉進(jìn)行離子交換制得氟硼酸型2，2日韩欧美久久精品影视大全免费观看，6小草在线免费观看av，6-四甲基-N-氧自由基哌啶負(fù)載離子液體TEMPO-IL。

Several transient compounds were synthesized by the homo- and heterogeneous reactions of reactive halogen compounds, In-situ ultraviolet photoelectron spectroscopy and photoionization mass spectroscopy as well as theoretical calculations were used to study their molecular structures, stability and molecular orbital properties, their electronic structures and geometric structures were obtained for the first time; Simultaneously, the electronic structure and thermal dissociation of acetyl peroxynitrate and trifluoroacetyl peroxynitrate which have great importance in the atmospheric chemistry were studied; The substituent effects of series of halopyridines and halothiophenes were studied by the ultraviolet photoelectron spectroscopy method for the first time. The atmospheric chemical reaction between peroxyacetyl radicals with IO radicals as well as the dissociation of the most stable isomer of CH3COIO3 were calculated by density functional theory, it was found that the CH3COOIO2 isomer may be act as a new reservoir of inorganic iodine in the stratosphere.

通過活性鹵素的系列均相與非均相化學(xué)反應(yīng)合成了幾種瞬態(tài)物種黑人一级婬片A片AAA毛片99，采用原位紫外光電子能譜和光電離質(zhì)譜結(jié)合量子化學(xué)理論計(jì)算對(duì)化合物的分子結(jié)構(gòu)aa视频在线网站、穩(wěn)定性以及分子軌道特性進(jìn)行了研究，首次獲得了這些物種的電子結(jié)構(gòu)和幾何結(jié)構(gòu)的信息欧美亚洲日韩；同時(shí)研究了大氣中有重要作用的乙酰過氧硝酸酯和三氟乙酰過氧硝酸酯的電子結(jié)構(gòu)性質(zhì)及熱解過程99在线视屏；采用紫外光電子能譜手段首次研究了系列鹵代吡啶和噻吩的取代基效應(yīng)；通過量子化學(xué)理論計(jì)算研究了乙豕犯咔迦肟谠谙撸基過氧自由基與IO自由基的大氣化學(xué)反應(yīng)及其最穩(wěn)定異構(gòu)體CH3COOIO2的解離av在线免费资源，發(fā)現(xiàn)該物種可能是無機(jī)碘化合物在平流層中的儲(chǔ)庫物種。

Major procurement of goods: a three-chlorosilanes, dichloromethane, AE activity ester, 3-iodine Silane, special acid, pentyl chloride, triethylamine, thiadiazole, tetrazolylazo acid, 2 - Acetamide, tetrahydrofuran, the four-guanidine, isopropanol, five phosphorus trichloride, sodium vary bitter, acid, sodium phenylacetate, 6-2 silicon n-amine, Ethylacetoacetate , Methyl isobutyl ketone, potassium dihydrogen phosphate, aluminium oxide, DL methionine, N, N-dimethylaniline, NN-diethyl aniline, 4 sodium EDTA, Anhydrous sodium sulfate, ammonium sulfate, potassium sulfate, sodium acetate, sodium carbonate, DMC, formic acid, sodium chloride medicinal, oxalate, protopine, acetone, alcohol, acetic acid, vinegar Ethyl, butyl acetate, methanol, ethanol (anhydrous, industrial, medicinal), formaldehyde, Ye Jian (30%), hydrochloride (industrial-grade, refined grade, reagent level), sulfate (98%), Ammonia, calcium carbonate, chlorine dioxide, 6 - APA ,7-ACA ,7-ADCA ,7-ANCA, sulbactam, ceftazidime activity ester, Deng salt (hydroxymethyl-K, acid precursors Potassium, sodium dihydrogen methyl), resin, the enzyme, water treatment agent, Xiao Mo agent, demulsifier, flocculants, activated carbon, all kinds of medicinal materials, All kinds of additives

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The major contents in this thesis are described as follows:(1) Seven new thiol fluorescence reagents containing 2-phenylbenzoxazole (or 2-phenylbenzothiazole) derivatives or benzanthrone as fluorphore and iodinacetylamine or maleimide as reaction groups have been synthesized.

本論文的研究工作主要分為以下幾個(gè)方面：(1)以碘乙酰胺或馬來酰亞胺為反應(yīng)基團(tuán)和以2-芳基苯并噁唑類化合物或苯并蒽酮為熒光團(tuán)农村老熟女乱子视频，首次合成了七種新的碘乙酰胺類和馬來酰亞胺類巰基熒光試劑亚洲欧美日韩色图。

Methods: A model to evaluate lymphocyte proliferation stimulated with a polyclonal activator, concanavalin A, was established by vital dye carboxyl fluorescin diacetate succinmidyl ester labeling technique. Effects of the different doses of anisomycin on the lymphocyte proliferation were estimated by flow cytometry and MTT methods. The propidium iodide labeling technique was applied to assay the effect of the different doses of anisomycin on changes of the lymphocyte cell-cycle stimulated by ConA or by phorbol ester plus Ionomycin. The percentage of the expression level of CD69 and CD25 on the activated lymphocytes was evaluated by fluorescin-conjugated monoclonal antibody double labeling technique.

以活體染料羧基熒光素乙酰乙酸琥珀酰亞胺酯染色，建立在多克隆刺激劑刀豆蛋白A刺激下評(píng)價(jià)小鼠淋巴細(xì)胞增殖的模型黄色网址国产区，通過流式細(xì)胞術(shù)和MTT法分析茴香霉素在不同劑量下對(duì)淋巴細(xì)胞增殖的作用超碰巨乳伊人；采用碘化丙錠染色分析茴香霉素對(duì)ConA或佛波醇酯加離子霉素刺激的小鼠淋巴細(xì)胞周期變化的作用；利用熒光標(biāo)記的單克隆抗體雙染技術(shù)和流式細(xì)胞術(shù)觀察茴香霉素對(duì)小鼠CD3~+T細(xì)胞早期及中期活化標(biāo)志分子CD69和CD25表達(dá)的影響日本黄网址免费在线观看。

The famciclovir was synthesized from purine by a series of steps by Acylation, Decarboxylation, Reduction ,and so on; Derivatives of these intermediates is described from the 6-chloro- 9H- purin-2-amine as raw materials in different conditions when the iodine and bromide were synthesized with the addition of two intermediate 6-bromo-9H-purin-2-amine and 6-iodo-9H-purin-2-amine; There is elaborated from the main part of a acetophenone, urineaminohydrochloride, phenylhydrazine, ethyl acetoacetate as raw material through a series of reactions to synthetic 3-phenyl-4-formylphenyl pyrazole and 5-chloro-3-methyl-1-phenyl-1H-pyrazole-4-aldehyde two pyrazole aldehyde, and then with 2-amino-6-chlorine-9-(2-methicillin-oxo-co-methyl-4-yl) purine reaction of the two new pyrazole purine Schiff bases.

本論文主是采用以鳥嘌呤為原料九九精品在线观看，經(jīng)過一系列的酰基化亚洲国产一区二区乱999，脫羧A∨女人网，還原等反應(yīng)作用下最終得到了產(chǎn)物2-氨基-9-(4-乙酰氧基-3-乙酰氧基甲基丁基)嘌呤；其中的中間體衍生物主要是闡述從以2-氨基-6-氯鳥嘌呤為原料通過在不同的條件下進(jìn)行溴代與碘代分別合成了另外兩種中間體2-氨基-6-溴鳥嘌呤及2-氨基-6-碘鳥嘌呤久久黄片18；還有一部分主要是闡述從以苯乙酮日韩欧美色，鹽酸氨基脲，苯肼三级黄色A片，乙酰乙酸乙酯為原料通過一系列的反應(yīng)先合成3-苯基-4-醛基吡唑及5-氯-3-甲基-1-苯基-1H-吡唑-4-甲醛這兩個(gè)吡唑醛亚洲国产欧美在线人网站，然后再與2-氨基-6-氯-9-(2-甲氧羰基丁酸甲酯-4-基)嘌呤反應(yīng)得到了兩個(gè)新型的吡唑嘌呤席夫堿

At 60 ℃ the reaction of 1-O-alkyl-2-O-acetyl-3-O-trityl glycerol with iodine/methanol system removed trityl and acetyl and gave 1-alkyl glycerol. But at r.t. the reaction only removed trityl and gave two isomers 1-O-alkyl-2-O-acetyl glycerol and 1-O-alkyl-3-O-acetyl glycerol.

1-烷氧基-2乙酰氧基-3-三苯甲氧基甘油醚與碘/甲醇體系反應(yīng)，在60 ℃時(shí)亚洲人兽网，同時(shí)發(fā)生了脫三苯甲基及乙跄腥颂焯猛谙吖劭词悠担基，在室溫下亚洲黄色在线视频观看网站，僅脫三苯甲基免费人成视频在线，但乙酰基在反應(yīng)過程中發(fā)生了部分轉(zhuǎn)移国产粉嫩出水在线播放，產(chǎn)生了兩個(gè)異構(gòu)體人人干99。

acetyl iodide：碘化乙酰

acetyl hydroperoxide 過乙酸 | acetyl iodide 碘化乙酰 | acetyl ketene 二酮

acetyl iodide：乙酰碘

acetyl hydrate 醋酸 | acetyl iodide 乙酰碘 | acetyl iso-eugenol 乙跹侵拮耘牧砝嘈∷底酆贤记基異丁香酚

acetyl iodide：乙酰碘;碘化乙蹙辆涟试赐基

乙酰丁香酚;乙酸丁香酚酯 acetyl eugenol; eugenol acetate | 乙酰氟 acetyl fluoride | 乙酰碘;碘化乙酰基 acetyl iodide

acetoin; 3-hydroxybutan-2-one：乙踉谙叱蒩欧美；谆状?3-羥-2-丁酮

乙酰肼 acetohydrazine | 乙豕谙?1人妖；谆状?3-羥-2-丁酮 acetoin; 3-hydroxybutan-2-one | 乙酰碘胺;N-碘乙酰胺 acetoiodoamide; N-iodoacetamide

acetol; hydroxypropanone：乙酰甲醇;羥丙酮

乙酰碘胺;N-碘乙酰胺 acetoiodoamide; N-iodoacetamide | 乙酰甲醇;羥丙酮 acetol; hydroxypropanone | 乙酰丙二酸 acetomalonic acid

acetyliodide：碘化乙酰

acetylide 乙炔化合物 | acetyliodide 碘化乙酰 | acetylisoeugenol 乙酰異丁子香酚

acetyliodide：乙酰碘

acetylindophenol | 乙酰靛酚 | acetyliodide | 乙酰碘 | acetylisable | 可乙跹侵夼访廊蘸缬白帜徊豢ǎ化的

ethanoyl iodide：乙酰碘

ethanoyl chloride乙酰氯 | ethanoyl iodide乙酰碘 | ethanoylation乙酰化<作用>

ethanoyl chloride：乙酰氯

ethanoyl bromide乙酰溴 | ethanoyl chloride乙酰氯 | ethanoyl iodide乙酰碘

ethanoyl peroxide; acetyl peroxide：過氧化乙酰

碘化乙酰;乙酰碘 ethanoyl iodide; acetyl iodide | 過氧化乙酰 ethanoyl peroxide; acetyl peroxide | 乙烯 ethene; ethylene