The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

結(jié)果表明該晶系屬單斜晶系，空間群P2(1)/c亚洲色天堂网，晶胞參數(shù)：a=848.46(3)pm午夜理论一级，b=681.54(3)pm，c=1967.16(8)pm国产一级黄片不卡免费视频，α=90°一级黄色毛片免费在线观看，β=95.8210(10)°，γ=90°一级精品视频在线观看，Z=4色五月夫网站，R_1=0.0279国产youjizz，wR_2=0.0724，Cu原子位于輕微變形的四方錐場底心，底面被氮原子http//www.色.com日本、酚氧原子、甘氨酸羧基的一個氧原子和一個水分子氧原子占據(jù)欧美大片aaaaa级，而甘氨酸羧基的另一個氧原子占據(jù)相鄰分子的錐頂，因而形成一維鏈狀結(jié)構(gòu)日韩新片免费无码观看；合成了單核雙聚配合物Na_2[Cu_2_2]·2H_2O 久久精品官网，銅三核配合物Cu_3_2·5H_2O和銅鋅異三核配合物ZnCu_2_2·5H_2O天天操操操，并用元素分析，IR光譜欧美天天搞网站，電子光譜和磁化率測定對配合物的組

The metal ions of the dinuclear copper complex of [Cu_2_2Cl_4] are linked by two N~1,N~2 1,2,4-triazole bridges,and the central Cu ions have distorted trigonal bipyramid geometries. The central Cu ion of [CuL22]·H2O has a centrosymmetric and distorted tetragonal-octahedral geometry. The metal ions of the dinuclear manganese complex of [Mn_2L_2_2Cl_2(H_2O)_2] are bridged by two chlorine atoms, and the central Mn ions have distorted tetragonal-octahedral geometries. Part III.

配合物[Cu_2_2Cl_4]是通過配體L的1999视频在线观看，2黄色美女福利视频，4-三唑環(huán)上兩個氮原子(N~1国产aav，N~2)橋聯(lián)形成的雙橋雙核配合物久久夜晚黄色视频，每個中心銅離子都具有畸變的三角雙錐構(gòu)型；配合物[CuL22]·H_2O的中心銅離子具有中心對稱的畸變八面體構(gòu)型成长黄色在线视频免费；配合物[Mn2L2_2Cl_2(H_2O)2]是通過兩個氯原子橋聯(lián)形成的雙橋雙核配合物色8久久人人97超碰香蕉987，每個中心錳離子都具有畸變的八面體構(gòu)型。

In this study aldylencdithiomethylene Malonic acid acts as the main coordination agents and compound iron ion have been synthesized by the means of solution, As a result ,the 1D polymer is obtained.

本論文采用常規(guī)的溶液合成方法毛片一级一区免费网站，首先設(shè)計合成了一個以含有二硫縮烯酮結(jié)構(gòu)的丙二酸類配體和過渡金屬鐵離子的單核配合物欧洲欧美精品VA在线观看，再以此單核配合物作為配體設(shè)計合成了三個異多核配合物和配位聚合物。

In this project, a series of novel polypyridine ligands and their ruthenium complexes were synthesized. The scope of this work is focused on the construction of multinuclear complexes, the controlling of electron and energy transfer in polynuclear complexes, NLO materials and molecular recognition, The results should be of value in further understanding the properties of the Ru complex, as well as laying the foundation for the rational design of Molecular devices based on Ru complexes.

本課題的主要目的是應用化學手段95热全部视频在线观看，設(shè)計合成出一系列結(jié)構(gòu)新穎的多吡啶配體及其釕配合物涩涩涩视频在线，在多核配合物的構(gòu)筑、電子和能量轉(zhuǎn)移調(diào)控欧美日韩国产一级婬片、非線性光學材料和分子識別等方面進行重點研究欧洲特级黄色网站，旨在進一步豐富和發(fā)展釕多吡啶配合物化學。

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),99视频有精品你懂的、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本論文主要包括以下三部分：一黄色视频污污、合成得到了一個草酰胺配體硝酸鹽的單晶結(jié)構(gòu)，[H_4dmaeoxd](NO_3)_2 (1)免黄片视频在线观看；通過調(diào)控金屬離子的種類免费久久精品国产片72、端基配體、抗衡陰離子国产36区、溶劑免费三级日欧美色性片、pH值等條件定向合成了四個反式草酰胺橋聯(lián)雙核銅配合物：[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)男女男精品视频网在线观看、国产精品群交电影在线免费观看、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5)日韩精品视频久久久免费观看；四個順式草酰胺橋聯(lián)同/異雙核配合物：[NiNi_2](ClO_4)_2 (6)国产男女激情一区二区、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)a级线手机免费观看、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9)一级A片全网免费观看；三個一維聚合物： [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)欧美另类精品一区二区三区、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12)97亚洲熟妇自偷自拍另类图片；一個二維聚合物： [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13)999Av天堂网；單核釩配合物[VO(H_2O)]·2H_2O (14)婷婷综合性、草酸根橋聯(lián)雙核鋅配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康銅配合物[Cu_2]·2DCM (16)，利用元素分析国产精品全网在线观看、摩爾電導18禁黄网站禁片流畅观看、紅外光譜、電子光譜和單晶X-射線衍射對上述所得化合物進行了結(jié)構(gòu)表征91原视频在线播放，探討了結(jié)構(gòu)影響因素人妻三级视频，并研究了其超分子結(jié)構(gòu)。

Six new ligands and 2 mononuclear,5 binuclear,8 tetranuclear complexes all of which are new havebeen synthesised and characterized by elementalanalysis,electric conductance and IR,UV-Vis spactr-oscopic methods.

本文主要研究多核配合物中的磁交換相互作用婷婷5月天综合色色。共合成了6個新配體，2個單核99久久一级黄视频。5個雙核和8個四核配合物更多国产精品，并用元素分析，紅外人人操人人爱爱，紫外一可見国产级特妇黄A片。

The main contributions of this thesis are:(1) Seven mononuclear complexes of tetradentate ligand NTB have been obtained using N〓 or SCN〓 as the additional ligand;(2) Seventeen binuclear complexes of Fe , Zn , Co , Cu have been designed and the complexes of Co , Cu exhibit antiferromagnetic properties;(3) Changing the bridged-ligand such as PO〓, CO〓, o-phth, mai, Ag (CN 〓, Au 〓, etc , fourteen tetranuclear complexes of polypridine ligand have been synthesized;(4) Two antiferromagnetic 1D chain complexes of KH〓pdc ligand have been prepared from hydrothermal reactions; in addition, one ferromagnetic 1D chain copper complex of tpdp which is bridged by oxalate has been obtained.

本論文的主要貢獻為：(1)合成了配體NTB的七個新型單核配合物；(2)合成了十七個鐵在线观看中文字幕亚洲、鋅www.aaa4a.com、鈷及銅系列混橋雙核配合物，其中雙核鈷和雙核銅配合物為反鐵磁偶合欧美一级二级在线；(3)選用多吡啶配體tpdp和TPA黄色视频在线观看免费入口，改變橋聯(lián)配體，合成了十個四核配合物91日韩在线观看视频；(4)選擇配體KH〓pdc一级黄色片欧美，采用水熱合成方法得到了反鐵磁性一維鏈狀錳、銅配合物欧美一区二区色视频；以草酸根為橋聯(lián)配體欧美自拍日韩经典，合成了配體tpdp的一維鏈狀銅配合物，該化合物為鐵磁偶合欧美一级在线看片，文獻較少報道亚洲日韩中文字幕一区二区。

Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.

1獲得了多個文獻首報和罕見的特殊結(jié)構(gòu)的配合物：兩個同時含有堿金屬-過渡-稀土金屬的獨特的九核配合物；兩個具有孔道的稀土-過渡金屬異四核配合物亚洲激情图片小说视频区；草酰胺類〓四核配合物免费一国产一级A片户外；兩個由雙核配合物通過疊氮和單個氯原子連成的四核配合物，尤其是以單個氯橋相連的化合物非常少見av网站有哪些；一個由弱配鍵和氫鍵連成的具有一維波浪形結(jié)構(gòu)的配合物亚州图片在线；一個通過配位鍵和氫鍵連成的二維配位聚合物。

Metal complex and metallomicelle as model compounds for artificial enzyme have been widely and extensively studied. In this dissertation, a series of homo- and hetero-dinuclear oxamido-bridged complexes have been synthesized, and the catalytic hydrolyses of carboxylic acid esters and phosphate by these complexes have been systematically investigated, and the catalytic mechanisms have also been dissected.

金屬配合物及金屬膠束作為人工酶的模型化合物受到廣泛而深入的研究99精品自拍视频在线播放，本文通過合成一系列的草酰胺橋聯(lián)同核和異核雙核配合物www色色色色色色，較為系統(tǒng)地研究了它們催化羧酸酯、磷酸酯水解反應的動力學，探討了它們的作用機制亚洲黄色欧美；同時华人社区福利导航，本文還探索了將金屬膠束這一較為成功的水解酶模擬模型應用于過氧化物酶模擬研究的可行性。

This dissertation aims at finding anticancer and antibacterial polynuclear complexes targeting DNA with high activity and low toxicity. Sixteen compounds were synthesized, and characterized by means of X-ray single crystal diffraction, elemental analysis, molar conductivity and IR, and the influencing factors on structures of the compounds have been investigated. The actions of these compounds to DNA were also investigated by spectral, electrochemical and hydromechanical methods.

本論文以DNA為靶點免费欧美日韩一区二区视频，以尋找新結(jié)構(gòu)類型的高效一级a爱大片免费观看、低毒的抗癌、抗菌多核配合物為目標91超碰在线播放，從分子設(shè)計出發(fā)美女黄污视频在线播放，共合成得到了16個化合物的單晶結(jié)構(gòu)，對其進行了結(jié)構(gòu)表征美日韩国产综合一区www，探討了結(jié)構(gòu)影響因素婷婷五月情，并研究了其超分子結(jié)構(gòu)；采用紫外-可見吸收光譜法一夲道一区二区免费视频、熒光光譜法先锋影音资源小说、電化學和粘度法，從分子水平上研究了所得配合物與DNA的相互作用黄网站色视；在細胞水平上黄色视频免费观看日本欧美www，研究了草酰胺橋聯(lián)雙核配合物的抗菌和抗腫瘤活性。

cytogamy：胞質(zhì)配合

文章摘要:對上海四膜蟲(Tetrahymena shanghaiensis)有小核細胞和無小核細胞的接合過程進行了跟蹤觀察,發(fā)現(xiàn)在四膜蟲中也存在胞質(zhì)配合(cytogamy). 在接合對中,有小核細胞一方可以完成正常的減數(shù)分裂過程,既有配子核的形成性爱毛片无码在线观看、配子核的融合、配子核分裂,

dien：二亞乙基三胺

合成了二亞乙基三胺(dien)和咪唑為配體的兩個銅(Ⅱ)單核配合物[(dien)Cu](ClO4)2欧美在线黄片小视频、[(dien)Cu imH](ClO4)2和一個非對稱性的咪唑橋聯(lián)銅鋅異雙核配合物[(dien)Cu im Zn(tren)](ClO4)3,

fertilization：受精作用

粗絲期檢控點(pachytene checkpoint)之分子作用機制減數(shù)分裂(meiosis)在真核生物有性繁殖中扮演決定性的角色,一次減數(shù)分裂包含了一次DNA復制,卻有二次染色體分離,因此配子內(nèi)的染色體數(shù)目得以減半,配合受精作用(fertilization)而維持子代染色體數(shù)

NW：美國西北航空公司

憑借與國際知名承運人良好穩(wěn)固的合作基礎(chǔ),我們已經(jīng)建立與包括中國國際航空公司(CA)在线看欧美性爱、美國西北航空公司(NW)、中國南方航空公司(CZ)你懂的的网站、深圳翡翠航空公司(JI)等航空巨擎的良好配合,并取得核心包板代理資格,

partition wall：隔間墻

系安全相關(guān)且須符合安全停機之地震於管制限值,亦即在發(fā)生喪失爐水事故(LOCA)時,能防止放射性Wall)一级毛片不卡视频在线、下乾井(Lower Dr ywell)人員及設(shè)備進出通道、隔膜地板核四廠RCCV Wall 在配合其周邊之隔間墻(Partition Wall)及相C1017 及其表Table 1 的規(guī)定,