Aim To study whether the derivative of in-dol-3-glyoxylic acid amide induced apoptosis on human galactophore cancer HeLa cells line in vitro and the feasible mechanisms of apoptosis.

目的 研究吲哚3-草酰胺衍生物YB-13在體外試驗(yàn)中誘導(dǎo)宮頸癌細(xì)胞株發(fā)生凋亡及其作用機(jī)制欧美熟妇free性XXXX。

Studies on Synthesis and Crystal Structure of N, N'-Bis(4-Hydroxy-3-Methoxybenzyl) Oxalamide

篇名 N，N'-雙（4-羥基－3-甲氧基苯甲基）草酰胺的合成及晶體結(jié)構(gòu)研究

DFT Study on Heterobinuclear Cu-Co Complex of N,N'-bis (3-carboxyl Salicyl Aminal Ethylene) Oxalamide

篇名 N，N'-雙（3-羧基水楊醛叉縮胺乙基）草酰胺Cu-Co異雙核配合物的密度泛函研究

The new oxalamide bridging ligands N, N'-bis (4-hydroxy-3-methoxy-benzyl) oxalamide (H4LB) was designed and synthesized.

設(shè)計(jì)合成一種新型對(duì)稱的草酰胺橋聯(lián)配體：N99久久精品无码专区，N'-二（4-羥基－3-甲氧基苯甲基）草酰胺配體(H4LB)。

The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.

晶體結(jié)構(gòu)研究表明配體H4L為順式橋聯(lián)分子91干屄，晶體中存在兩種氫鍵亚州黄色一级无码，一種是草酰胺基團(tuán)的O原子與苯環(huán)上的酚羥基形成O-H…O氫鍵[d=2.906(2)三级片精品视频，∠O-H…O=151.8°]；另一種是草酰胺基團(tuán)的氨基與相鄰草酰胺基上的O原子形成N-H…O氫鍵[d=2.849(2)多人乱P过瘾视频免费，∠N-H…O=158.7°]chaopeng97，通過上述兩種氫鍵將化合物H4LB連接成二維網(wǎng)絡(luò)結(jié)構(gòu)。

Through condensing o-aminobenzoic acid, ethyl oxalyl chloride and ethylenediamine(or 1,2-propylenediamine), two new ligands N-benzoato-N′-(2- aminoethyl)oxamido(H3oxbe) and N-benzoato-N-(2-amino-2-methylethyl)oxamido(H3oxbt) have been synthesized. Their mononuclear complexes Na·1.5H2O and Na·1.5H2O have also been obtained.

2以鄰氨基苯甲酸青青久操手机在线中文字幕、草酸乙酯酰氯和乙二胺(或1国产一级A片AV在线，2-丙二胺)縮合制得了兩種具有不對(duì)稱草酰胺結(jié)構(gòu)配體N-(2-苯甲酰基)-N&-(2-氨乙基)草酰胺(H3oxbe)和N-(2-苯甲豕夥研越籥片；?-N&-(2-氨丙基)草酰胺(H3oxbt)一a级黄片免费看，并得到了它們的單核配合物：Na·1.5H2O和Na·1.5H2O。

The effects of acidity and temperature on the fluorescent characteristics of N-N-bis-(O-Carboxylphenyl)-Oxamide have been studied in details.

本文首次研究了酸度最新欧美操屄视频、溫度對(duì)對(duì)稱草酰胺：N-N-二－鄰羧基苯基草酰胺熒光特性的影響50熟妇。

For AP based propellants, oxamide (NH 2 CO 2 ) 2 is particularly effective in reducing burn rate, without sacrificing performance.

為鴨基于推進(jìn)劑，草酰胺（信息NH 2的CO 2 ） 2 毛片黄色网站在线观看，特別是有效地減少燒傷率男人的天堂视频，在不犧牲性能。

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),永久女性毛片免费看、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本論文主要包括以下三部分：一黄色网站黄色网址视频、合成得到了一個(gè)草酰胺配體硝酸鹽的單晶結(jié)構(gòu)，[H_4dmaeoxd](NO_3)_2 (1)2019人妻巨乳超碰；通過調(diào)控金屬離子的種類欧美天欧美天堂aⅴ在线、端基配體、抗衡陰離子理论午夜、溶劑美国一级强奸片、pH值等條件定向合成了四個(gè)反式草酰胺橋聯(lián)雙核銅配合物：[Cu_2_2](ClO_4)_2 (2)、[Cu_2_2](ClO_4)_2 (3)国产操妓女的屄视频、中文字幕永久在线、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5)人人澡人人摸人人干；四個(gè)順式草酰胺橋聯(lián)同/異雙核配合物：[NiNi_2](ClO_4)_2 (6)免费观看国产黄页网站、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)a级线手机免费观看、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9)一级A片全网免费观看；三個(gè)一維聚合物： [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)欧美性爱在线综合、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12)偷拍一级黄片操操操视频；一個(gè)二維聚合物： [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13)久久一级黄片羞羞；單核釩配合物[VO(H_2O)]·2H_2O (14)国产视频福利网站、草酸根橋聯(lián)雙核鋅配合物[Zn_2_4](ClO_4)_2·H_2O (15)在线视频自拍网、美洛西康銅配合物[Cu_2]·2DCM (16)，利用元素分析一级黄片在线免费看、摩爾電導(dǎo)国产精品久久97、紅外光譜、電子光譜和單晶X-射線衍射對(duì)上述所得化合物進(jìn)行了結(jié)構(gòu)表征真人性交A级片播放,，探討了結(jié)構(gòu)影響因素无码一级做a爱过程免费不卡片，并研究了其超分子結(jié)構(gòu)。

Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.

1獲得了多個(gè)文獻(xiàn)首報(bào)和罕見的特殊結(jié)構(gòu)的配合物：兩個(gè)同時(shí)含有堿金屬-過渡-稀土金屬的獨(dú)特的九核配合物无码老熟妇色视频；兩個(gè)具有孔道的稀土-過渡金屬異四核配合物看免费的黄色片；草酰胺類〓四核配合物；兩個(gè)由雙核配合物通過疊氮和單個(gè)氯原子連成的四核配合物国产无码视频网站，尤其是以單個(gè)氯橋相連的化合物非常少見小视频试看入口；一個(gè)由弱配鍵和氫鍵連成的具有一維波浪形結(jié)構(gòu)的配合物；一個(gè)通過配位鍵和氫鍵連成的二維配位聚合物亚洲国产一级av。

oxalic acid dianilide：乙二酰胺苯;草酰胺苯

乙二酸二烯丙酯;草酸二烯丙酯 oxalic acid diallyl ester | 乙二酰胺苯;草酰胺苯 oxalic acid dianilide | 乙二酸二異戊酯;草酸二異戊酯 oxalic acid diisoamyl ester

oxalamide：草酰胺

oxalaldehyde 草醛 | oxalamide 草酰胺 | oxalate 草酸 草酸鹽 草酸鹽酯 乙二酸鹽

butyl oxamate：草酰胺酸丁酯;乙酰胺酸丁酯

丁基鄰[草(之上)+叨]基醚;丁基鄰甲苯基醚 butyl o-tolyl ether | 草酰胺酸丁酯;乙酰胺酸丁酯 butyl oxamate | 丁氧乙醇 butyl oxitol; butyl glycol

ethyl oxamate：草酰胺酸乙酯

草乙酸[二]乙酯 ethyl oxalacetate | 草酰胺酸乙酯 ethyl oxamate | 乙醚;二乙基醚 ethyl oxide

oxamic acid：草酰胺酸

草酰脲 oxalylurea; parabanic acid | 草酰胺酸 oxamic acid | 草酰胺酰肼;胺草酰肼 oxamic acid hydrazide; semioxamazide; oxamic hydrazide

oxamic acid hydrazide; semioxamazide; oxamic hydrazide：草酰胺酰肼;胺草酰肼

草酰胺酸 oxamic acid | 草酰胺酰肼;胺草酰肼 oxamic acid hydrazide; semioxamazide; oxamic hydrazide | 草酰胺;乙二酰二胺 oxamide

oxamide：草酰胺

oxamicacid 草氨酸 | oxamide 草酰胺 | oxanilide 草酰替苯胺

oxamide：草酰胺;乙二酰二胺

草酸;草酸鹽 oxalate | 草酰胺;乙二酰二胺 oxamide | 鹽酸羥胺 oxammonium hydrochloride

ethanediamide; oxamide：乙二酰胺;草酰胺

乙二醛;草醛 ethanedial; glyoxal | 乙二酰胺;草酰胺 ethanediamide; oxamide | 乙二腈;氰;二氰 ethanedinitrile; cyanogene; dicyanogene

pentanamide; valeramide：戊酰胺;纈草酰胺

戊醛;纈草醛 pentanal; valeraldehyde | 戊酰胺;纈草酰胺 pentanamide; valeramide | 戊烷 pentane