The rheological character of a polymer often appears as shear-thinning. Most polymers behaviour in a solution can be explained by the polymer chain or hard sphere theory. Other than that, shear-thickening polymer solution also exists. Its behavior can be explained by dilatant theory, which suggests that the shear-thickening of the solution is due to the swelling of the polymer particles. This phenomenon often occurs in suspension or emulsion. Solution exhibits a mixed behavior can also be found whose behavior is such that shear-thinning occurs under low shear force and shear-thickening occurs under high shear force. Under this circumstance, the viscosity versus shear force graph exhibits a spoon shaped curve. The rheological study can be applied to the dispersion of paint which can predict the dispersion effect of various polymer materials in solution.

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It is included that 4-5 types of active sites exist in the catalytic system and the active site produced polymer with low molecular weight is easy to be activiated while TEA is used as the cocatalyst. While TIBA, the active site produced polymer with high molecular weight and seldom active site produced polymer with low one is prone to be activiated. MAO tends to activiate the active site produced polymer with middle-level molecular weight. In TEA-TIBA catalytic system, TEA and TIBA activiate the corresponding active site and the weight of every active site gradationally varied with the change of the ratio of the two cocatalysts. And the activity of the active site produced polymer with high molecular weight is proportion to the concentration of TIBA.

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The conclusions were as follows: theνO-H andνC=O IR absorption maxima shifted towards higher wave numbers after imprinting 17β-estradiol on TFMAA-co-TRIM copolymer with the red shift of theνO-H groups being apparent after precipitation polymerization for 16h while that forνC=O groups being observed after polymerization for 24h. A strong interaction between TFMAA and 17β-estradiol was confirmed by the high selectivity for 17β-estradiol, as indicted by the values of the separation factor of isomers of 17β-estradiol/17α-estradiol (2.28) and the imprinted factor (3.01). Particle diameter of TFMAA-co-TRIM polymer was between 300 nm and 1.5μm, which suited well for solid phase sorbent throughout at low column pressure. The recognition of imprinting TFMAA-co-TRIM polymer for sterol molecules was driven by enthalpy eluted with acetronitile, and low temperature was in favor of the separation of sterol structure analogues on imprinting column. TFMAA-co-TRIM polymer possessed of determinate anti-heat stability, with melting point beginning at 255.84℃, Tp=257.40℃, control TFMAA-co-TRIM polymer and imprinting TFMAA-co-TRIM polymer were respectively decompounded at 267.79℃and 343.11℃, and solid micro-extraction noddle prepared by the special polymerization also showed definite recognition for 17β-estradiol by GC/MS detecting at 270℃. By selection of various washing and elution solvents, elution reagents of close polymerization system were of more advantage in template molecules retention and recognition on molecularly imprinted solid phase extraction column. At a certain extent, progesterone, 17α-estradiol, 17β-estradiol and 4-androstene-3, 17-dione could be intercepted on the MISPE column. Especially, MISPE had high selectivity for progesterone, and imprinting TFMAA-co-TRIM polymer could achieve adsorption balance within 50 min by absorption kinetics test for 17β-estradiol. However, MISPE column showed better selectivity and enrichment property for 17β-estradiol than C18 and CSPE columns according to the data from HPLC and GC/MS analyses. Recovery of 17β-estradiol on MISPE column was up to 85.5% while when prime extracting solution of milk powder was sampled, the recovery of CSPE and C18 columns were 43.7% and 30.7%, respectively.

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The dynamics and heat transfer on the spinning line during the air drawing process are discussed in detail, mainly relating the forces acting upon the polymer along the spinning line and the expressions of the air drawing coefficient C〓 and heat transfer coefficient h. By introducing the power-law model as the constitutive equation to describe the theological properties of polymer melt and considering the changing of the density and specific heat capacity of polymer melt at constant pressure with the polymer temperature, the former model of polymer air drawing is improved and a complete polymer air drawing model is established, which is integrated with the model of air jet flow field of dual slot die.

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The oil-displacing agents for crosslinked polymer oil-displacing system are mainly as follows:the polymer containing monomers with heat resistance and salt tolerance ,zwitterion polymer,hydrophobically associating water-soluble polymer,polymer complex system,and comb polymer.

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The features of AAA adsorbed on the ethylatedβ-CD polymer were similar with those of the parentalβ-CD polymer, but theadsorption ratios of AAA on the ethylatedβ-CD polymer were higher than those of the parentalβ-CD polymer. It may be due to the strengthened hydrophobic interactions between AAA and the ethylatedβ-CD polymer, which was caused by the ethylation of the parentalβ-CD polymer.

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Along the same lines, Polymer Vision, based in the Netherlands, demonstrated a device the size of a BlackBerry that has a five-inch rolled-up screen that can be unfurled for reading.

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In the dissertation, a new stabilization method, equal-density method was adopted to prepare modified asphalts with storage stability at high temperature. In this method, a compound was prepared by premixing polymer and filler, and the compound was mixed with asphalt to prepare Polymer-Modified Asphalt by changing the ratio of polymer and filler. The asphalts with good storage stability were formed with the addition of filler, by regulating the density difference between polymer and asphalt. With identifying the effect of composition factor and the technique conditions on mechanical properties of polymer/filler compound and the molecular distribution of the polymer, identifying the effect of composition factor and the technique conditions on the properties and structure of polymer/filler modified asphalt, Styrene-Butadiene-Styrene copolymer, Low Density PolyEthylene, Styrene-Ethylene-Butadiene-Styrene block copolymer modified asphalts with good storage stability and performance were prepared. Rheological method, gel content analysis and swelling measurement were adopted to elucidate the interaction between the polymer and filler. Filler reduced the difference between the polymer and asphalt with the premixing technique, which led to the improvement of the storage stability of the modified asphalts. The thermo-oxidative aging process of base asphalt and PMA were studied and the effect of antioxidant additives on the base asphalt and PMA were analyzed.

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Through the analysis of De, an alternative mechanism interpreting of the"overshoot"phenomena can be obtained: when the diffusing time of small molecular penetrants is shorter than relaxation time of the involved polymer, small molecular substance penetrates into the polymer quickly and its concentration reached a maximum, then the swelling of the polymer by the small molecules makes the chain structure of the polymer relaxed, thus the free volume in polymer matrix, which is occupied by small molecule, decreased, and will squeeze part of the small molecular substance out of the polymer, and therefore overshoot behavior can be observed.

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