The copper atom is in a planar coordination site of [N_2O_2] and it devites from the mean plane by only 0.80 pm. Byπ-πstacking interactions, a alabastrine structure was obtained.(2)Schiff-base complex [Cu(H_2O)]·H_2O, where H3GS is the 3-carboxyl -salicylidene glycine, was synthesized and characterized by elemental analysis, IR spectra and single-crystal analysis. The crystal belongs to monoclinic system, space group P2(1)/c, a=848.46(3)pm, b=681.54(3)pm, c=1967.16(8)pm,β=95.8210(10)°, Z=4, R_1=0.0279, wR_2=0.0724. The copper atom is in a square-pyramidal field with the base

結(jié)果表明該晶系屬單斜晶系另类视频午夜，空間群P2(1)/c人人超碰人人爽人人添，晶胞參數(shù)：a=848.46(3)pm，b=681.54(3)pm日韩毛片一区二区免费，c=1967.16(8)pm外国A级免费毛片，α=90°，β=95.8210(10)°久久Se精品一区二区影院，γ=90°免费观看黄色视频A级，Z=491肉色长靴丝袜国产在线，R_1=0.0279，wR_2=0.0724国产福利91精品一区二区，Cu原子位于輕微變形的四方錐場(chǎng)底心日韩人成精品视频免费播放在线，底面被氮原子、酚氧原子日韩快播自拍图片在线观看网站、甘氨酸羧基的一個(gè)氧原子和一個(gè)水分子氧原子占據(jù)6080午夜久草，而甘氨酸羧基的另一個(gè)氧原子占據(jù)相鄰分子的錐頂，因而形成一維鏈狀結(jié)構(gòu)美女奶头无遮挡网站视频免费观看；合成了單核雙聚配合物Na_2[Cu_2_2]·2H_2O 欧美熟妇被草，銅三核配合物Cu_3_2·5H_2O和銅鋅異三核配合物ZnCu_2_2·5H_2O，并用元素分析亚洲欧美黑人性暴力猛交群，IR光譜人人操人人看人操，電子光譜和磁化率測(cè)定對(duì)配合物的組

The metal ions of the dinuclear copper complex of [Cu_2_2Cl_4] are linked by two N~1,N~2 1,2,4-triazole bridges,and the central Cu ions have distorted trigonal bipyramid geometries. The central Cu ion of [CuL22]·H2O has a centrosymmetric and distorted tetragonal-octahedral geometry. The metal ions of the dinuclear manganese complex of [Mn_2L_2_2Cl_2(H_2O)_2] are bridged by two chlorine atoms, and the central Mn ions have distorted tetragonal-octahedral geometries. Part III.

配合物[Cu_2_2Cl_4]是通過配體L的1，2国产精品美女视频一区二区，4-三唑環(huán)上兩個(gè)氮原子(N~191KCM国产在线精品，N~2)橋聯(lián)形成的雙橋雙核配合物，每個(gè)中心銅離子都具有畸變的三角雙錐構(gòu)型女生的奶罩(黄片)；配合物[CuL22]·H_2O的中心銅離子具有中心對(duì)稱的畸變八面體構(gòu)型久久久夜色精品国产热热；配合物[Mn2L2_2Cl_2(H_2O)2]是通過兩個(gè)氯原子橋聯(lián)形成的雙橋雙核配合物，每個(gè)中心錳離子都具有畸變的八面體構(gòu)型看无码国产毛片视频直播。

In this study aldylencdithiomethylene Malonic acid acts as the main coordination agents and compound iron ion have been synthesized by the means of solution, As a result ,the 1D polymer is obtained.

本論文采用常規(guī)的溶液合成方法香蕉高清影视一级在线观看，首先設(shè)計(jì)合成了一個(gè)以含有二硫縮烯酮結(jié)構(gòu)的丙二酸類配體和過渡金屬鐵離子的單核配合物，再以此單核配合物作為配體設(shè)計(jì)合成了三個(gè)異多核配合物和配位聚合物人人操,人人弄。

In this project, a series of novel polypyridine ligands and their ruthenium complexes were synthesized. The scope of this work is focused on the construction of multinuclear complexes, the controlling of electron and energy transfer in polynuclear complexes, NLO materials and molecular recognition, The results should be of value in further understanding the properties of the Ru complex, as well as laying the foundation for the rational design of Molecular devices based on Ru complexes.

本課題的主要目的是應(yīng)用化學(xué)手段看免费三级黄片不卡视频，設(shè)計(jì)合成出一系列結(jié)構(gòu)新穎的多吡啶配體及其釕配合物，在多核配合物的構(gòu)筑五月婷婷丁香综合网、電子和能量轉(zhuǎn)移調(diào)控国产真人无码作爱兔费视频、非線性光學(xué)材料和分子識(shí)別等方面進(jìn)行重點(diǎn)研究，旨在進(jìn)一步豐富和發(fā)展釕多吡啶配合物化學(xué)欧美一级久久。

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),日韩不卡在线视频、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本論文主要包括以下三部分：一、合成得到了一個(gè)草酰胺配體硝酸鹽的單晶結(jié)構(gòu)国产一级a免费无码视频，[H_4dmaeoxd](NO_3)_2 (1)A片在线一区看；通過調(diào)控金屬離子的種類中文字幕xfplay男人资源站、端基配體www欧美系列、抗衡陰離子、溶劑青青青国产中文在线视频免观看、pH值等條件定向合成了四個(gè)反式草酰胺橋聯(lián)雙核銅配合物：[Cu_2_2](ClO_4)_2 (2)国产福利最新地址发布页8010、[Cu_2_2](ClO_4)_2 (3)欧美日大黄片、、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)免费黄色a片大全、[Cu_2_2(H_2O)_2] (5)国产91精品宾馆；四個(gè)順式草酰胺橋聯(lián)同/異雙核配合物：[NiNi_2](ClO_4)_2 (6)、[CuNi_2](ClO_4)_2·2CH_3OH (7)国产黄片精品在线、[CuZn_2]-(ClO_4)_2·2H_2O (8)国产原创精品在线、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9)；三個(gè)一維聚合物： [Cu_2]_n·nH_2O (10)www.人妻一级黄四色AV日韩AV、[Cu_2(H_2O)_2-]_n·4nH_2O (11)一级A片福利片、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12)；一個(gè)二維聚合物： [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)国产综合久偷自。2nH_2O (13)wwwwxxxx国产；單核釩配合物[VO(H_2O)]·2H_2O (14)、草酸根橋聯(lián)雙核鋅配合物[Zn_2_4](ClO_4)_2·H_2O (15)亚洲精品免费线视频观看视频、美洛西康銅配合物[Cu_2]·2DCM (16)黄色精品国产，利用元素分析、摩爾電導(dǎo)色综合久久一区二区观看、紅外光譜日韩精品碰碰视频、電子光譜和單晶X-射線衍射對(duì)上述所得化合物進(jìn)行了結(jié)構(gòu)表征，探討了結(jié)構(gòu)影響因素一级毛片一级毛片AAAA级，并研究了其超分子結(jié)構(gòu)一级免费视频国产。

Six new ligands and 2 mononuclear,5 binuclear,8 tetranuclear complexes all of which are new havebeen synthesised and characterized by elementalanalysis,electric conductance and IR,UV-Vis spactr-oscopic methods.

本文主要研究多核配合物中的磁交換相互作用。共合成了6個(gè)新配體操美女视频在线网站，2個(gè)單核天堂干屄免费视频。5個(gè)雙核和8個(gè)四核配合物，并用元素分析www.日本在线播放，紅外国产综合一区二区三区精品，紫外一可見。

The main contributions of this thesis are:(1) Seven mononuclear complexes of tetradentate ligand NTB have been obtained using N〓 or SCN〓 as the additional ligand;(2) Seventeen binuclear complexes of Fe , Zn , Co , Cu have been designed and the complexes of Co , Cu exhibit antiferromagnetic properties;(3) Changing the bridged-ligand such as PO〓, CO〓, o-phth, mai, Ag (CN 〓, Au 〓, etc , fourteen tetranuclear complexes of polypridine ligand have been synthesized;(4) Two antiferromagnetic 1D chain complexes of KH〓pdc ligand have been prepared from hydrothermal reactions; in addition, one ferromagnetic 1D chain copper complex of tpdp which is bridged by oxalate has been obtained.

本論文的主要貢獻(xiàn)為：(1)合成了配體NTB的七個(gè)新型單核配合物久久国内免费黄色；(2)合成了十七個(gè)鐵最新国产裸模视频视频在线、鋅、鈷及銅系列混橋雙核配合物色婷婷五月亚洲一区二区91，其中雙核鈷和雙核銅配合物為反鐵磁偶合亚洲欧美视频网站；(3)選用多吡啶配體tpdp和TPA，改變橋聯(lián)配體十八禁无码，合成了十個(gè)四核配合物一级A色片；(4)選擇配體KH〓pdc，采用水熱合成方法得到了反鐵磁性一維鏈狀錳综合性天堂在线、銅配合物久久九一；以草酸根為橋聯(lián)配體94自拍视频，合成了配體tpdp的一維鏈狀銅配合物，該化合物為鐵磁偶合欧美骚逼，文獻(xiàn)較少報(bào)道日本mmm。

Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.

1獲得了多個(gè)文獻(xiàn)首報(bào)和罕見的特殊結(jié)構(gòu)的配合物：兩個(gè)同時(shí)含有堿金屬-過渡-稀土金屬的獨(dú)特的九核配合物；兩個(gè)具有孔道的稀土-過渡金屬異四核配合物啊好爽用力插视频；草酰胺類〓四核配合物日韩成人播放无码AV；兩個(gè)由雙核配合物通過疊氮和單個(gè)氯原子連成的四核配合物，尤其是以單個(gè)氯橋相連的化合物非常少見女人一级毛多A片；一個(gè)由弱配鍵和氫鍵連成的具有一維波浪形結(jié)構(gòu)的配合物午夜视频久久久久一区免费；一個(gè)通過配位鍵和氫鍵連成的二維配位聚合物。

Metal complex and metallomicelle as model compounds for artificial enzyme have been widely and extensively studied. In this dissertation, a series of homo- and hetero-dinuclear oxamido-bridged complexes have been synthesized, and the catalytic hydrolyses of carboxylic acid esters and phosphate by these complexes have been systematically investigated, and the catalytic mechanisms have also been dissected.

金屬配合物及金屬膠束作為人工酶的模型化合物受到廣泛而深入的研究无码在线观看毛片，本文通過合成一系列的草酰胺橋聯(lián)同核和異核雙核配合物一级毛片一级毛片视频片，較為系統(tǒng)地研究了它們催化羧酸酯、磷酸酯水解反應(yīng)的動(dòng)力學(xué)黄色视频人人干人，探討了它們的作用機(jī)制在线图区；同時(shí)，本文還探索了將金屬膠束這一較為成功的水解酶模擬模型應(yīng)用于過氧化物酶模擬研究的可行性欧美噪B视频69。

This dissertation aims at finding anticancer and antibacterial polynuclear complexes targeting DNA with high activity and low toxicity. Sixteen compounds were synthesized, and characterized by means of X-ray single crystal diffraction, elemental analysis, molar conductivity and IR, and the influencing factors on structures of the compounds have been investigated. The actions of these compounds to DNA were also investigated by spectral, electrochemical and hydromechanical methods.

本論文以DNA為靶點(diǎn)欧美性爱一级免费大片，以尋找新結(jié)構(gòu)類型的高效、低毒的抗癌午夜精品无码高清在线、抗菌多核配合物為目標(biāo)精品无码一级毛片，從分子設(shè)計(jì)出發(fā)，共合成得到了16個(gè)化合物的單晶結(jié)構(gòu)激情性爱在线观看，對(duì)其進(jìn)行了結(jié)構(gòu)表征亚洲是图宗合网，探討了結(jié)構(gòu)影響因素，并研究了其超分子結(jié)構(gòu)国产精品不卡无毒在线观看；采用紫外-可見吸收光譜法免费视频XNXXCOM、熒光光譜法、電化學(xué)和粘度法精品国偷自产在线视频500，從分子水平上研究了所得配合物與DNA的相互作用欧美淫乱a片；在細(xì)胞水平上，研究了草酰胺橋聯(lián)雙核配合物的抗菌和抗腫瘤活性为工室特级黄色A片。