A method for determination of basic nitrogen-containing compounds in mainstream smoke was established. In the condition of basic substance barium hydroxide powder and extractant chloroform, 18 basic nitrogen-containing compounds were analyzed by gas chromatography-selective ion monitored-mass spectrometry, such as pyridine, 2-methylpyridine, 2-methylpyrazine, quinoline and indole, etc.

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Methods Starting from 2-chloro-4-nitrophenol and 2- pyridine hydrochlorid, 3-chloro-4-(pyridin-2-ylmethoxy) aniline was obtained via etherization and reduction. The obtained aniline coupled with N-(4-chloro-3-cyano-7-ethoxyquinolin-6-yl) acetamide to give 4-[3-chloro-4-(2-pyridylmethoxy) phenylamino]-3-cyano-7-ethoxy-6-N-acetylaminoquinoline. And then it was deacetylated, followed by reacting with4- but-2-enoyl chloride to yield the target compound neratinib.

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Cobalt forms colored complexes with pyridire,,β-picoline and γ-picoline in aqueous solutions.

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Picoline was treated with hydrogen peroxide to form intermediate N-oxide-3- methylpyridine then chloridized with benzoyl chloride to form 2-chloro-5-methylpyridine.

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Based on broad information collection, author compared and studied on the old synthesis process, and proposed the better process that started from benzyl chloride, then according to the sequence of " synthesis of benzylamine, synthesis of N-benzyl-N--acetamine, synthesis of 2-chloro-5-methylpridine ,2-chloro-5-trichloromethylpyridine,2-chloro-5-trifluropyridine " five steps to get the final product, CTFP.

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Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

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But on the industry, many with the alkyl bandaging, such as bandaging , ergadebidi...

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Based on the research and development of synthesis of halogenated pyridines the paper chose the electrochemical reduction as a research direction, and to 3,4,5,6–tetrachloropicolinic acid, pentachloropyridine, 3,4,5,6-tetrachloro-2-trichloromethylpyridine for raw materials, the reduction behavior on silver and carbon -containing silver electrode was mainly studied.

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A process for synthesis of-2-{[4-(3-methoxypropoxy)-3-methyl-pyridin-2-yl]methyl- sulfinyl}-1H-benzimidazole from 2,3-lutidine was studied.

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The effects of pyridine substitutive derivations on the metabolic pathway of Blakeslea Trispora, were studied such as 2,6-dimethylpyridine,2,5-dimethylpyridine, 2-amino-6-methylpyridine and tobacco dust which contains mainly 3-pyridine substitutive derivation.

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