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A few years later things changed and the Friars seemed to possess more space within the basilica. In fact the Russian Archimandritte Gretenius who came in pilgrimage in the first years of the XV century says that within the basilica live permanently a Greek priest, a Georgian, a Frank, an Armenian, a Jacobite and an Abissinian. He states also that on the aedicula on the tomb there was a picture of the Risen Christ with a kneeling St. Francis. He also says that the Friars of the Chord (as the Franciscans became to be know) possessed Calvary together with the Armenians. All this was probably due to the firmans issued by sultan Barquq (1382-1399) in favour of the Friars of the Holy Sepulchre.

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They are:In the third chapter, the crystal structures of these new dca complexes are described anddiscussed in detail. Besides two mononuclear complexes, 1 and 2, complexes 3～15 arecoordination polymer with novel and interesting structural characteristics. 3, 6, 7, 8, 9 are 1Dpolymers, 4 and 5 are of 2D extending structure, while 10, 11, 12, 13, 14, 15, 16, 17 form thefirstly reported series heteronuclear dca coordination polymer, in which (except 10) differentbuilding blocks, with different metal ions in them, construct interesting architecture, like α-and β-type 〓 chains, ladder chain 〓, scaffold structure of 12, and "sandwich"layer structure in 15 and 16, etc..

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In the fourth chapter , we studied the resonance light scattering spectral characteristic of patent blueⅤ- Cetyltrimethyl ammonium bromide-nucleic acid system, and the elementary reaction mechanism with absorption spectra method and 1H NMR spectra method. Another new determination method of nucleic acid at nanogram level was established.

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