Aim To study whether the derivative of in-dol-3-glyoxylic acid amide induced apoptosis on human galactophore cancer HeLa cells line in vitro and the feasible mechanisms of apoptosis.

目的 研究吲哚3-草酰胺衍生物YB-13在體外試驗中誘導(dǎo)宮頸癌細(xì)胞株發(fā)生凋亡及其作用機制。

Studies on Synthesis and Crystal Structure of N, N'-Bis(4-Hydroxy-3-Methoxybenzyl) Oxalamide

篇名 N，N'-雙（4-羥基－3-甲氧基苯甲基）草酰胺的合成及晶體結(jié)構(gòu)研究

DFT Study on Heterobinuclear Cu-Co Complex of N,N'-bis (3-carboxyl Salicyl Aminal Ethylene) Oxalamide

篇名 N，N'-雙（3-羧基水楊醛叉縮胺乙基）草酰胺Cu-Co異雙核配合物的密度泛函研究

The new oxalamide bridging ligands N, N'-bis (4-hydroxy-3-methoxy-benzyl) oxalamide (H4LB) was designed and synthesized.

設(shè)計合成一種新型對稱的草酰胺橋聯(lián)配體：N，N'-二（4-羥基－3-甲氧基苯甲基）草酰胺配體(H4LB)自拍偷拍午夜视频。

The structure analysis indicates that the reverse symmetry ligand H4LB molecules are linked into a 2D supermolecular network by two types of hydrogen bonds. One type occurs between the oxalamide oxygen group and the phenol hydroxyl qroup of the nearest molecule with d=2.906(2) and ∠O-H…O=151.8°. The other type is between the oxalamide nitrogen group and the oxalamide oxygen group of anther molecule with d=2.849(2),∠N-H…O=158.7°.

晶體結(jié)構(gòu)研究表明配體H4L為順式橋聯(lián)分子，晶體中存在兩種氫鍵0792dmz.com，一種是草酰胺基團的O原子與苯環(huán)上的酚羥基形成O-H…O氫鍵[d=2.906(2)九九自拍偷拍，∠O-H…O=151.8°]；另一種是草酰胺基團的氨基與相鄰草酰胺基上的O原子形成N-H…O氫鍵[d=2.849(2)国产免费A片地址，∠N-H…O=158.7°]涩涩的网站，通過上述兩種氫鍵將化合物H4LB連接成二維網(wǎng)絡(luò)結(jié)構(gòu)90后久久综合九色综合。

Through condensing o-aminobenzoic acid, ethyl oxalyl chloride and ethylenediamine(or 1,2-propylenediamine), two new ligands N-benzoato-N′-(2- aminoethyl)oxamido(H3oxbe) and N-benzoato-N-(2-amino-2-methylethyl)oxamido(H3oxbt) have been synthesized. Their mononuclear complexes Na·1.5H2O and Na·1.5H2O have also been obtained.

2以鄰氨基苯甲酸、草酸乙酯酰氯和乙二胺(或1国产黄页在线观看黄A∨，2-丙二胺)縮合制得了兩種具有不對稱草酰胺結(jié)構(gòu)配體N-(2-苯甲趺夥崖闾寤仆驹谙吖劭矗基)-N&-(2-氨乙基)草酰胺(H3oxbe)和N-(2-苯甲酰基)-N&-(2-氨丙基)草酰胺(H3oxbt)亚洲国产二区，并得到了它們的單核配合物：Na·1.5H2O和Na·1.5H2O免费无码毛片免费看。

The effects of acidity and temperature on the fluorescent characteristics of N-N-bis-(O-Carboxylphenyl)-Oxamide have been studied in details.

本文首次研究了酸度、溫度對對稱草酰胺：N-N-二－鄰羧基苯基草酰胺熒光特性的影響很操亚洲美女。

For AP based propellants, oxamide (NH 2 CO 2 ) 2 is particularly effective in reducing burn rate, without sacrificing performance.

為鴨基于推進劑在线视频xx，草酰胺（信息NH 2的CO 2 ） 2 ，特別是有效地減少燒傷率欧美一级A片裸体视频，在不犧牲性能九九视频在线观看黄片。

Finally, the cytotoxic and antibacterial activities of the oxamido-bridged binuclear complexes were studied in vitro.. This dissertation consists of three sections as follows:1. The crystal structure of a oxamide dinitrate,(1) [H_4dmaeoxd](NO_3)_2 H_2dmaeoxd = N,N\'-bis[2-ethyloxamide, has been obtained. The diversity of complexes with different structures is carried out by successful synthetic strategy of controlling species of metal ions, counter anions, pH values and solvents in the course of synthesis. Four dinuclear complexes bridged by trans-dmaeoxd2-: [Cu_2_2](ClO_4)_2 (2), [Cu_2_2](ClO_4)_2 (3),、[Cu_2(Me_2phen)_2](ClO_4)_2 (4), [Cu_2_2(H_2O)_2] (5); Four dinuclear complexes bridged by cis-dmaeoxd2-: [NiNi_2](ClO_4)_2 (6), [CuNi_2](ClO_4)_2·2CH_3OH (7), [CuZn_2]-(ClO_4)_2·2H_2O (8), [Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9); three 1-D polynuclear complexes: [Cu_2]_n·nH_2O (10), [Cu_2(H_2O)_2-]_n·4nH_2O (11), [Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12); one 2-D polynuclear complex,[Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n).2nH_2O (13); the others: [VO(H_2O)]·2H_2O (14), [Zn_2_4](ClO_4)_2·H_2O (15), [Cu_2]·2DCM (16) have been synthesized and characterized by X-ray single crystal diffraction, elemental analysis, IR spectra.

本論文主要包括以下三部分：一中文字幕综合国产、合成得到了一個草酰胺配體硝酸鹽的單晶結(jié)構(gòu)黄色欧美网站，[H_4dmaeoxd](NO_3)_2 (1)；通過調(diào)控金屬離子的種類人人爽碰97青青草原、端基配體日本在线免费小电影、抗衡陰離子、溶劑亚洲免费网址你懂的、pH值等條件定向合成了四個反式草酰胺橋聯(lián)雙核銅配合物：[Cu_2_2](ClO_4)_2 (2)欧美性爱导航、[Cu_2_2](ClO_4)_2 (3)、一级地二级黄色视频、[Cu_2(Me_2phen)_2](ClO_4)_2 (4)、[Cu_2_2(H_2O)_2] (5)亚洲愉拍一区二区精品；四個順式草酰胺橋聯(lián)同/異雙核配合物：[NiNi_2](ClO_4)_2 (6)在线观看视频线上观看黄片平台、[CuNi_2](ClO_4)_2·2CH_3OH (7)、[CuZn_2]-(ClO_4)_2·2H_2O (8)毛片官网在线、[Cu(H_2O)Ni_2](ClO_4)_2.0.5CH_3OH (9)欧美日本韩国A片三级片色哟哟；三個一維聚合物： [Cu_2]_n·nH_2O (10)、[Cu_2(H_2O)_2-]_n·4nH_2O (11)人人做人人爽人人澡狠狠添、[Cu_2(H_2O)]_n(NO_3)_n·2nH_2O (12)黄色大片最新网址品尚网；一個二維聚合物： [Cu_6_3(μ_3-OH)_2(H_2O)_2]_n(ClO_4)_(4n)。2nH_2O (13)有黄有色的视频免费在线看；單核釩配合物[VO(H_2O)]·2H_2O (14)偷玩朋友的醉酒人妻中文字幕,、草酸根橋聯(lián)雙核鋅配合物[Zn_2_4](ClO_4)_2·H_2O (15)、美洛西康銅配合物[Cu_2]·2DCM (16)三级片视频午夜，利用元素分析性交毛片视频免费看、摩爾電導(dǎo)欧洲精品乱码久久久久、紅外光譜、電子光譜和單晶X-射線衍射對上述所得化合物進行了結(jié)構(gòu)表征福利视频一区二区三区，探討了結(jié)構(gòu)影響因素欧美另类在线观看，并研究了其超分子結(jié)構(gòu)。

Several novel structures have been determined: Unique ninenuclear complexesincorporating 3d, 4f metals with a sodium ion center, the sodium ion may be serve as atemplate in the formation of these novel complexes; Novel tetranuclear 〓complexes with channels formed by intermolecular weak interactions; First 〓type tetranuclear complex; Peculiar "dimer of dimers" complexes derived frombinuclear complex; Unusual one-dimensional wave chain formed by weakcoordination bonds and hydrogen bonds and two dimensional coordination polymerconstructed through coordination bonds and hydrogen bonds.

1獲得了多個文獻首報和罕見的特殊結(jié)構(gòu)的配合物：兩個同時含有堿金屬-過渡-稀土金屬的獨特的九核配合物91在线人人艹；兩個具有孔道的稀土-過渡金屬異四核配合物一级A片国产孕妇；草酰胺類〓四核配合物；兩個由雙核配合物通過疊氮和單個氯原子連成的四核配合物中文字幕观看，尤其是以單個氯橋相連的化合物非常少見欧美高潮抽搐免费A片大全；一個由弱配鍵和氫鍵連成的具有一維波浪形結(jié)構(gòu)的配合物；一個通過配位鍵和氫鍵連成的二維配位聚合物一级免费黄色视频一级免费黄色视频。