The presence of REE tetrad effects in apatites and whole rocks of S-type granites has been reported by Sha and Chappell (1999) and Zhao et al.(1999), respectively. The REE tetrad effect in minerals, such as apatite, spessartite, beryl, alkali feldspar and spodumene, from all zones of Altay No. 3 pegmatite has been found remarkable, and the fractionations among isovalent incompatible elements in these minerals are also significant. This paper puts forward that the REE tetrad effect is one of the basic features of peraluminous melts and the origin of REE tetrad effect might be probably related to some processes prior to the formation of pegmatite magma. The immiscibile liquid separation between silicate melt and hydrosaline melt may be responsible for it.

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